| match | Time | Day | ||
 Andreeva M Medvedev D | 0 - 2 2-4 3-5 |  Danilovic O Djokovic N | 22:00 | 19.08.2025 |
 Rybakina E Fritz T | 0 - 2 4-2 4-2 |  Errani S  Vavassori A | 18:00 | 19.08.2025 |
 LMcNally C Musetti | 2 - 0 3-5 2-4 |  Osaka N Monfils G | 18:00 | 19.08.2025 |
 Raducanu E Alcaraz C | 2 - 0 4-2 4-2 |  Pegula J Draper J | 21:00 | 19.08.2025 |
 Bencic B Zverev A | 2 - 0 4-0 5-3 |  Collins D Hrrison C | 22:00 | 19.08.2025 |
 Keys M | 2 - 0 4-1 4-2 |  Swiatek I Ruud C | 19:00 | 19.08.2025 |
 Anisimova A Rune H | 2 - 0 4-2 5-4 (7-2) |  Townsend T Shelton B | 21:00 | 19.08.2025 |
 Muchova K Rublev A | 0 - 2 2-4 4-5 (4-7) |  Williams V Opelka R | 19:00 | 19.08.2025 |
| match | Time | Day | ||
Muchova K Rublev A | 2 - 0 4-1 5-4 (7-4) | Errani S Vavassori A | 20:45 | 19.08.2025 |
LMcNally C Musetti | 2 - 0 4-1 4-2 |  Swiatek I Ruud C | 20:45 | 19.08.2025 |
Andreeva M Medvedev D | 2 - 0 4-1 4-1 |  Pegula j  Draper j | 21:45 | 19.08.2025 |
 Townsend Shelton B | 2 - 0 4-1 5-4 (7-2) |  Collins D Harrison C | 22:45 | 19.08.2025 |
| match | Time | Day | ||
 Draper j | 2 - 1 3-5 5-3 10-8 | Swiatek I Ruud C | 02:00 | 21.08.2025 |
 Errani S Vavassori A | 0 - 2 2-4 2-4 | Collins D Harrison C | 03:30 | 21.08.2025 |
| match | Time | Day | ||
| 1 - 2 3-6 7-5 6-10 | Swiatek I Ruud C | 05:10 | 21.08.2025 |
